卤水中溶解性有机质的光谱学性质和光降解行为研究     

杨克利  董亚萍  李武  彭姣玉  刘海宁 《地学前缘》2021,28(6):187-195

卤水中溶解性有机质(dissolved organic matter,DOM)会对盐田日晒工艺和产品质量产生不利影响,如盐田卤水的蒸发速率减缓、蒸发度减小以及提取的矿物产品带有刺鼻的气味、浓重的颜色等。因此,对具有资源开发利用价值的卤水体系中DOM结构和性质的研究可以为后续DOM的有效去除或在DOM共存体系中调控无机盐结晶工艺路线提供有效的指导意见。本文以自然界中广泛存在的两种不同类型的卤水体系,即盐湖卤水DOM(SLDOM)和油田卤水DOM(OFDOM)为研究对象,采用溶解性有机碳(dissolved organic carbon,DOC)分析、光谱学分析和平行因子分析等手段对DOM的含量、分子量分布特征、光谱学结构和光降解行为开展了研究。DOC和荧光分析表明SLDOM和OFDOM的DOC含量和生物指数(BIX)值相似;与OFDOM相比,SLDOM的腐质化指数(HIX)值和高分子量组分(HMW)比例偏高;特别吸收光谱(SUVA₂₅₄)和糖类化合物含量检测结果表明,SLDOM和OFDOM的HMW组分中含有的芳香类和糖类化合物所占比例比低分子量组分(LMW)高;三维荧光谱图分析(EEM)结果表明,SLDOM主要以腐殖质类物质为主,而OFDOM以蛋白质类组分为主。此外,DOM的荧光组分在不同分子量中的分布也存在明显差异:对于SLDOM,富里酸主要分布在HMW DOM中,而腐殖酸主要在LMW DOM中;对于OFDOM,芳香胺类蛋白组分主要分布在HMW DOM中,色氨酸和酪氨酸类蛋白组分主要分布在LMM DOM中。在光降解实验中,SLDOM和OFDOM的DOC含量随光照时间增加而逐渐减少,分别下降了29.32%和15.11%。进一步的分析表明,光照过程中两种卤水中糖类化合物均减少,小分子量的DOM优先分解。此外,在光照过程中SLDOM芳香类化合物增加,腐质化程度基本不变;OFDOM芳香类化合物减少,腐质化程度增加。EEM平行因子分析(PARAFAC)结果表明,SLDOM荧光组分在光降解过程中荧光强度增加,而OFDOM荧光强度减少。  相似文献   

不同要素谱逼近对高分辨区域数值模式梅雨模拟的改进   总被引：1，自引：0，他引：1  

董美莹  陈锋  冀春晓 《气象》2019,45(5):593-605

为改进高分辨率区域数值天气预报模式雨带模拟偏差,利用WRF模式探讨了不同要素及其组合谱逼近方法对2015年浙江典型梅雨天气预报性能的影响。结果表明:(1)不同单要素逼近对梅雨模拟效果影响差异明显,风场逼近对模拟结果改进较大,高度场逼近对结果略有改善,而温度场逼近主要表现为负效应;风场组合了其他要素的逼近效果与单要素类似,故将水平风场谱逼近确定为最优方案。(2)最优方案对梅雨期间形势场各要素改进程度的排序为纬向风、经向风、相对湿度、温度场和高度场;三个特征层850、500、200 hPa各要素平均的均方根误差(相关系数)分别降低了(增加了)24. 1%(13.6%)、22.7%(21.7%)和13.0%(12.2%);且改进幅度随预报时效的延长而增加,这主要与区域模式内部大尺度系统的误差随积分时间增长有关。(3)典型个例分析显示,最优方案在较好订正低层风场及切变线动力条件的基础上,经过数值模式各物理过程的协同积分也修正了高湿区等关键热力因子,最终改进了高分辨率区域模式的梅雨模拟。  相似文献   

四川地形扰动对降水分布影响          下载免费PDF全文

王成鑫  高守亭  冉令坤  陈悦丽 《应用气象学报》2019,30(5):586-597

引入一维加权平均的谱分析方法定量研究四川地形强迫对该区域降水分布的影响。结果表明:纬向地形和冬季降水谱峰锁相于同一波长（475.8 km）,呈共振关系,地形与其他季节降水呈漂移关系,这与经向和纬向上环流变动有关,即冬季纬向环流占主导,纬向地形触发的大气波动对冬季降水策动作用大;夏季降水是各种不同尺度系统相互作用的结果,地形是重要因素之一。经向和纬向地形特征尺度分别为296.8 km和475.8 km,反映了地形强迫的中尺度特征,且纬向地形谱峰比经向大1个数量级,纬向强迫更明显。夏季降水谱峰比冬季大2个数量级,降水系统纬向特征尺度比冬季小约150 km,说明夏季在纬向地形强迫下,降水系统尺度减小的同时其强度大大增加,这在一定程度上可以解释中尺度对流性降水在夏季偏多。四川夏季最大降水位于雅安地区,其地形扰动比四川整体扰动更明显,故产生的降水也更大。夏季降水和经向地形锁相于同一波长（37.1 km）,经向地形对雅安夏季强降水起关键作用。  相似文献   

基于南海北部海区浮游植物吸收光谱斜率变化的粒级结构反演   总被引：1，自引：0，他引：1       下载免费PDF全文

王桂芬  曹文熙  周雯  梁少君  杨跃忠  赵俊 《热带海洋学报》2010,29(2):25-32

浮游植物的粒级结构是一个重要的生物参数。基于南海北部海区不同水体环境下测量的生物光学数据, 作者深入研究了粒级结构对浮游植物吸收光谱的影响。结果表明, 选择443和510nm波段计算得到的浮游植物光谱斜率S对粒级结构的变化具有较高的敏感性, 其随着小型浮游植物比例的增大呈不断增加的趋势。S与水体叶绿素a浓度、浮游植物吸收系数(aph(443))之间表现出明显的正相关特征。以40%为界对不同粒级浮游植物的优势进行定义, 发现在S与叶绿素a浓度、aph(443)的关系分布中小型(Micro)和微微型(Pico)浮游植物占据优势的水体表现出较为明显的分界, 叶绿素a浓度和aph(443)分别在0.70mg•m-3和0.05m-1附近, 相应的S在0.0004(m•nm)-1左右。基于实测数据建立的遥感反射率蓝绿波段比值与S之间的统计关系, 决定系数高达0.91, 为从水色遥感数据反演浮游植物粒级结构提供了重要手段。  相似文献   

Attenuation of compressional waves in peridotite measured as a function of temperature at 200 MPa   总被引：3，自引：0，他引：3  

Hiroki Sato  I. Selwyn Sacks  Tsutomu Murase  Gregory Muncill  Hiroyuki Fukuyama 《Pure and Applied Geophysics》1988,128(1-2):433-447

A technique has been developed to determine attenuation in rocks at high temperature using a gas-media, high-pressure apparatus. A pulse transmission technique and a spectral ratio method are used to study compressional seismic properties of rocks. Seismic waves are transmitted to and from the sample through buffer rods of mullite. The effect of seismic wave reflections within the sample assembly are cancelled out by taking ratios of the spectra measured at different temperatures. In order to obtain good signal-to-noise ratio for resolving the attenuation at high pressure and temperature, special care is taken in the sample assembly and the ultrasonic coupling between the sample, buffer rods and transducers. A very tight connection of the sample-buffer rod-transducer is essential for obtaining high frequency signals (>300 kHz) at high temperature. A small mass is attached to each outside end of the transducer to drive low frequency signals (<250 kHz) into the sample. Before attenuation measurements, the sample and the buffer rods are tightly compacted in a platinum tube at high pressure and room temperature to ensure pressure seal of the sample assembly. The frequency range of measurement covers 50 to 450 kHz for the sample. Attenuation is very small in the buffer rod compared to the sample for the entire temperature range of the study. Because of the small attenuation, a wide frequency band of 50 kHz to 3.2 MHz can be covered for investigating the attenuation in the buffer rod. The technique has been used to measure attenuation at high confining pressure, and temperatures including sub- and hyper-solidus of upper mantle rocks. Therefore, effects of partial melting on attenuation can be studied.The method is applied to the attenuation measurement in a peridotite as a function of temperature to 1225°C at 200 MPa confining pressure. At high temperature, signal amplitude decays more rapidly at high frequency than at low frequency, from which attenuation (andQ) can be determined using a spectral ratio method. No frequency dependence ofQ is resolved for both the sample and the buffer rod over the entire temperature and frequency ranges of the measurement. The results show thatQ decreases rapidly with increasing temperature even in the temperature range below the solidus of peridotites. Such temperature sensitivity ofQ is probably more useful to probe thermal structure in the upper mantle than that of conductivity at temperatures below the solidus. The results in this study are compared with available seismic velocity, electrical conductivity and solidus data for peridotites, suggesting that there is no discontinuous change in both mechanical and electrical properties of peridotites at the solidus temperature. Even at hypersolidus temperatures, it appears that velocity drops and conductivity increases continuously (not abruptly) with increasing melt fraction. This implies that mechanical and electrical properties of the upper mantle will gradually change at the boundary where the geotherm crosses the solidus.  相似文献   

Global spectra of energy and enstrophy and their fluxes during July 1979     

S S Desai  S K Mishra 《Journal of Earth System Science》1993,102(2):329-350

Transient and stationary spectra of kinetic energy (KE), available potential energy (APE) and enstrophy (EN), and their spectral fluxes as a function of the two-dimensional wavenumbern were computed for July 1979. Triangular truncation at zonal wavenumber 42 was used for computation. The slopes of various spectra in the wavenumber range 14≤n≤25 were obtained by fitting a straight line in log-log scale by the least square method. The transientKE, APE andEN spectra in the lower (upper) troposphere had slopes −2·21 (−2·30), −2·65 (−2·64) and −0·36 (−0·46), respectively. The effect of stationary and divergent motion on the slope values was investigated. The possible correlation between the slope and percentage of transient component in the combined energy and enstrophy was examined to identify the transient motion of the atmosphere with the two-dimensional homogeneous isotropic turbulence. The vertically averaged slope of kinetic energy and enstrophy in the lower (upper) troposphere was close to the value at 700 (200) hPa level. The spectral fluxes of kinetic energy and enstrophy in the wavenumber range 14≤n≤25 satisfied, to a very rough approximation, the criteria of inertial subrange. The stationary fluxes were small. The estimated stationary-transient component of flux was larger, comparable and less than the corresponding transient flux of APE, KE and EN. Representative levels for computation of energy and enstrophy spectra and their fluxes in the lower and upper troposphere were identified.  相似文献   

The Fourier Integral Method: An efficient spectral method for simulation of random fields   总被引：4，自引：0，他引：4  

E. Pardo-Igúzquiza  M. Chica-Olmo 《Mathematical Geology》1993,25(2):177-217

The Fourier Integral Method (FIM) of spectral simulation, adapted to generate realizations of a random function in one, two, or three dimensions, is shown to be an efficient technique of non-conditional geostatistical simulation. The main contribution is the use of the fast Fourier transform for both numerical calculus of the density spectral function and as generator of random finite multidimensional sequences with imposed covariance. Results obtained with the FIM are compared with those obtained by other classic methods: Shinozuka and Jan Method in 1D and Turning Bands Method in 2D and 3D, the points for and against different methodologies are discussed. Moreover, with the FIM the simulation of nested structures, one of which can be a nugget effect and the simulation of both zonal and geometric anisotropy is straightforward. All steps taken to implement the FIM methodology are discussed.  相似文献   

Calculation of sensitivities for the frequency-domain electromagnetic problem   总被引：3，自引：0，他引：3  

P. R. McGillivray  D. W. Oldenburg  R. G. Ellis  T. M. Habashy 《Geophysical Journal International》1994,116(1):1-4

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精确高程异常的确定     

张克非 《武汉大学学报(信息科学版)》1990,(3)

本文在顾及局部地形改正、椭球改正及大气改正的情况下,采用实测数据,应用Meissel方法和Wenzel频谱分析方法,对某盆地边缘的高程异常进行了实际计算。并将计算结果同多普勒高程异常进行了比较,证明结果是良好的。此外还对我国精确高程异常的确定提出了一些建议。  相似文献   

陀螺经纬仪时间观测数据函数模型的研究     

李清泉 《武汉大学学报(信息科学版)》1990,(3)

本文运用最小二乘谱分析的原理,对陀螺经纬仪时间观测数据进行分析,提出了一种较以前采用的函数模型更为简便、实用的函数模型,并利用实测数据分析了测时定向方法的精度。  相似文献